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A century before the series' setting, after Kisuke Urahara created the Hōgyoku, an item he believed creates Soul Reaper and Hollow hybrids, Aizen began to experiment using the Soul Reapers that would become the Vizards. Among his test subjects was Shinji, who knew about Aizen, but learned too late that Aizen used his mistrust against him.
After arriving in Hueco Mundo, the group find themselves facing the Arrancars Demōra and Iceringer. Meanwhile, Orihime is brought before Aizen and is asked demonstrate her power by restoring Grimmjow's arm. Grimmjow then asks Orihime to restore his tattoo before killing Luppi to regain his rank among the Espadas. 28: Baron's Lecture Full-Course
Sōsuke Aizen, Gin Ichimaru, and Kaname Tōsen—the captains of squads Five, Three, and Nine respectively—eventually defect from the Soul Society at the time of Rukia's rescue, effectively interrupting Ichigo's battles, and enact a plan to gain greater power with the Arrancar. Aizen is brought into focus as the story's main antagonist.
Aizen appears with Gin and reveals his own betrayal, explaining to Hirako that his illusion-casting zanpakutō had disguised another person as a stand-in for himself during his interactions with Hirako all this time. Hirako and the rest of the group begin transforming into hollows, but Hirako manages to hang onto his consciousness.
Anticipating Aizen's attack, the Thirteen Court Squads had already been waiting for him by moving the entire Karakura Town to the Soul Society prior to his attack. When the Vizards join the remaining Soul Reapers, Gin reveals his agenda of killing Aizen. The latter uses the Hōgyoku to become a god-like being before killing Gin.
As Yamamoto stands before Aizen again, Wonderweiss unleashes the flames sealed in his body as he dies. Yamamoto uses his body to minimize the damage the explosion causes. Aizen approaches the immobile Yamamoto and prepares to finish him off, but Yamamoto uses his body as a catalyst for his Ittō Kasō, the forbidden kidō spell of sacrifice ...
The brazen coup attempt that took the life of Haitian President Jovenel Moïse holds all the elements of a three-act Shakespearean tragedy: plots and subplots, ambition and betrayal, gore and ...
Another of Aizen's early experiments in blending hollow and Soul Reaper abilities, created from Soul Reaper souls, White is a black-colored, horned, humanoid hollow. Years before the events of the series, White hunts Soul Reapers until he is defeated by the combined efforts of Isshin Shiba and Masaki Kurosaki.