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The standard molar entropy of a gas at STP includes contributions from: [2] The heat capacity of one mole of the solid from 0 K to the melting point (including heat absorbed in any changes between different crystal structures). The latent heat of fusion of the solid. The heat capacity of the liquid from the melting point to the boiling point.
The standard state of a material (pure substance, mixture or solution) is a reference point used to calculate its properties under different conditions.A degree sign (°) or a superscript Plimsoll symbol (⦵) is used to designate a thermodynamic quantity in the standard state, such as change in enthalpy (ΔH°), change in entropy (ΔS°), or change in Gibbs free energy (ΔG°).
The ideal gas equation can be rearranged to give an expression for the molar volume of an ideal gas: = = Hence, for a given temperature and pressure, the molar volume is the same for all ideal gases and is based on the gas constant: R = 8.314 462 618 153 24 m 3 ⋅Pa⋅K −1 ⋅mol −1, or about 8.205 736 608 095 96 × 10 −5 m 3 ⋅atm⋅K ...
Technical literature can be confusing because many authors fail to explain whether they are using the ideal gas constant R, or the specific gas constant R s. The relationship between the two constants is R s = R / m, where m is the molecular mass of the gas. The US Standard Atmosphere (USSA) uses 8.31432 m 3 ·Pa/(mol·K) as the value of R.
Molar heat content of four substances in their designated states above 298.15 K and at 1 atm pressure. CaO(c) and Rh(c) are in their normal standard state of crystalline solid at all temperatures. S 2 (g) is a non-physical state below about 882 K and NiO(g) is a non-physical state at all temperatures.
In a pure substance, μ is equal to the Gibbs energy G m for a mole of the substance, [2]: 207 and = = +, where T and P are the temperature and pressure, V m is the volume per mole and S m is the entropy per mole. [2]: 248
The Gas composition of any gas can be characterised by listing the pure substances it contains, and stating for each substance its proportion of the gas mixture's molecule count.Nitrogen N 2 78.084 Oxygen O 2 20.9476 Argon Ar 0.934 Carbon Dioxide CO 2 0.0314
24.71 0.1735 1-Hexanol [2] 31.79 0.1856 Hydrazine [2] 8.46 0.0462 Hydrogen: 0.2476 ... (where kmol is kilomoles = 1000 moles) References This page was last ...