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Phenolphthalein's pH sensitivity is exploited in other applications: concrete has naturally high pH due to the calcium hydroxide formed when Portland cement reacts with water. As the concrete reacts with carbon dioxide in the atmosphere, pH decreases to 8.5–9. When a 1% phenolphthalein solution is applied to normal concrete, it turns bright pink.
When atmospheric carbon dioxide (CO 2), or carbonate ions (HCO − 3, CO 2− 3 dissolved in water) diffuse into concrete from its external surface, they react with calcium hydroxide (portlandite, Ca(OH) 2) and the pH of the concrete pore water progressively decreases from 13.5 – 12.5 to 8.5 (pH of water in equilibrium with calcite).
Beside initially lowering the pH value of the concrete pore water, the main working mechanism of silica fume addition is to consume portlandite (the reservoir of hydroxyde (OH –) in the solid phase) and to decrease the porosity of the hardened cement paste by the formation of calcium silicate hydrates (C-S-H). However, silica fume has to be ...
Contact with wet concrete can cause skin chemical burns due to the caustic nature of the mixture of cement and water (including rainwater). Indeed, the pH of fresh cement water is highly alkaline due to the presence of free potassium and sodium hydroxides in solution (pH ~ 13.5). Eyes, hands and feet must be correctly protected to avoid any ...
A single concrete block, as used for construction. Concrete is a composite material composed of aggregate bonded together with a fluid cement that cures to a solid over time. . Concrete is the second-most-used substance in the world after water, [1] and is the most widely used building material
The water in the pores of Portland cement concrete is normally alkaline with a pH in the range of 12.5 to 13.5. This highly alkaline environment is one in which the steel rebar is passivated and is protected from corrosion. According to the Pourbaix diagram for iron, the metal is passive when the pH is above 9.5. [1]
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The pH at the equivalence point depends on how much the weak acid is consumed to be converted into its conjugate base. Note that when an acid neutralizes a base, the pH may or may not be neutral (pH = 7). The pH depends on the strengths of the acid and base.
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