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The amide group can be involved in hydrogen bonding to other nitrogen- and oxygen-containing species.. The predominant solid state form is 2-pyridone. This has been confirmed by X-ray crystallography which shows that the hydrogen in solid state is closer to the nitrogen than to the oxygen (because of the low electron density at the hydrogen the exact positioning is difficult), and IR ...
It is an electrophilic source of oxygen that reacts with enolates and related structures, and thus can be used for alpha-hydroxylation of carbonyl-containing compounds. [3] Other reagents used for alpha-hydroxylation via enol or enolate structures include Davis oxaziridine , oxygen , and various peroxyacids (see Rubottom oxidation ).
Pyridine (data page) ... 12.3 ε 0 at 25 °C Bond strength ... Table data obtained from CRC Handbook of Chemistry and Physics 44th ed. log 10 of Pyridine vapor pressure.
However, pyridine-3-sulfonic acid can be obtained. Reaction with the SO 3 group also facilitates addition of sulfur to the nitrogen atom, especially in the presence of a mercury(II) sulfate catalyst. [84] [93] In contrast to the sluggish nitrations and sulfonations, the bromination and chlorination of pyridine proceed well. [2]
3-Hydroxyisonicotinaldehyde (HINA), also known as 3-hydroxypyridine-4-carboxaldehyde, is a derivative of pyridine, with hydroxyl and aldehyde substituents. It has been studied as a simple analogue of vitamin B 6. In 2020, it was reported as having the lowest molecular weight of all dyes which exhibit green fluorescence. [2] [3]
4-Pyridone exists a keto-enol tautomerism with its enol tautomer 4-hydroxypyridine. In solution, the keto tautomer is favoured, [4] and the enol tautomer only becomes important in very dilute solutions or solutions of non-polar solvents.
Pyridinedicarboxylic acid is a group of organic compounds which are dicarboxylic derivatives of pyridine. Pyridinedicarboxylic acid comes in several isomers: Quinolinic acid (2,3-pyridinedicarboxylic acid) Lutidinic acid (2,4-pyridinedicarboxylic acid) Isocinchomeronic acid (2,5-pyridinedicarboxylic acid) Dipicolinic acid (2,6 ...
Chloro(pyridine)cobaloxime(III) is first reduced to Chloro(pyridine)cobaloxime(I) by sodium borohydride in alkaline solution, then an alkyl halide is added into the reaction mixture, and the desired Co-C bond is formed via a S N 2 reaction. This method can be used to produce cobaloximes containing a primary or a secondary alkyl substituent.