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Trimethylamine (TMA) is an organic compound with the formula N(CH 3) 3. It is a trimethylated derivative of ammonia. TMA is widely used in industry. [5] [6] At higher concentrations it has an ammonia-like odor, and can cause necrosis of mucous membranes on contact. [7] At lower concentrations, it has a "fishy" odor, the odor associated with ...
For example, NH 3 is a Lewis base, because it can donate its lone pair of electrons. Trimethylborane [(CH 3) 3 B] is a Lewis acid as it is capable of accepting a lone pair. In a Lewis adduct, the Lewis acid and base share an electron pair furnished by the Lewis base, forming a dative bond. [1]
Trimethylamine N-oxide (TMAO) is an organic compound with the formula (CH 3) 3 NO. It is in the class of amine oxides. Although the anhydrous compound is known, trimethylamine N-oxide is usually encountered as the dihydrate. Both the anhydrous and hydrated materials are white, water-soluble solids.
B(CH 3) 3 can form an adduct with ammonia: (NH 3):B(CH 3) 3. [13] as well as other Lewis bases. The Lewis acid properties of B(CH 3) 3 have been analyzed by the ECW model yielding E A = 2.90 and C A = 3.60. When trimethylborane forms an adduct with trimethylamine, steric repulsion between the methyl groups on the B and N results. The ECW model ...
[1] [2] [3] Introduced by Gilbert N. Lewis in his 1916 article The Atom and the Molecule, a Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. [4] Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond.
As a result, the lone pair of trimethylphosphine has predominantly s-character as is the case for phosphine, PH 3. [3] PMe 3 can be prepared by the treatment of triphenyl phosphite with methylmagnesium chloride: [4] 3 CH 3 MgCl + P(OC 6 H 5) 3 → P(CH 3) 3 + 3 C 6 H 5 OMgCl. The synthesis is conducted in dibutyl ether, from which the more ...
nh 3 + 3 c 2 h 5 oh → n(c 2 h 5) 3 + 3 h 2 o The pK a of protonated triethylamine is 10.75, [ 4 ] and it can be used to prepare buffer solutions at that pH. The hydrochloride salt , triethylamine hydrochloride (triethylammonium chloride), is a colorless, odorless, and hygroscopic powder, which decomposes when heated to 261 °C.
Methyl nitrate is a sensitive explosive.When ignited it burns extremely fiercely with a gray-blue flame. Methyl nitrate is a very strong explosive with a detonation velocity of 6,300 m/s, [8] like nitroglycerin, ethylene glycol dinitrate, and other nitrate esters.