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The reaction of fatty acids with base is the other main method of saponification. In this case, the reaction involves neutralization of the carboxylic acid. The neutralization method is used to produce industrial soaps such as those derived from magnesium, the transition metals, and aluminium.
The higher the saponification value, the lower the fatty acids average length, the lighter the mean molecular weight of triglycerides and vice versa. Practically, fats or oils with high saponification value (such as coconut and palm oil) are more suitable for soap making.
A handmade soap bar Two equivalent images of the chemical structure of sodium stearate, a typical ingredient found in bar soaps Emulsifying action of soap on oil. Soap is a salt of a fatty acid (sometimes other carboxylic acids) used for cleaning and lubricating products as well as other applications. [1]
Fatty acids are mainly used in the production of soap, both for cosmetic purposes and, in the case of metallic soaps, as lubricants. Fatty acids are also converted, via their methyl esters, to fatty alcohols and fatty amines, which are precursors to surfactants, detergents, and lubricants. [17]
Total fatty matter (TFM) is one of the most important characteristics describing the quality of soap and is always specified in commercial transactions. It is defined as the total amount of fatty matter, mostly fatty acids, that can be separated from a sample after splitting with a mineral acid, usually hydrochloric acid.
In fatty acids, unsaturation occurs mainly as double bonds which are very reactive towards halogens, the iodine in this case. Thus, the higher the iodine value, the more unsaturations are present in the fat. [1] It can be seen from the table that coconut oil is very saturated, which means it is good for making soap.
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The saponification of esters of fatty acids is an industrially important process, used in the production of soap. [24] Esterification is a reversible reaction. Esters undergo hydrolysis under acidic and basic conditions. Under acidic conditions, the reaction is the reverse reaction of the Fischer esterification.
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