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An enthalpy–entropy chart, also known as the H–S chart or Mollier diagram, plots the total heat against entropy, [1] describing the enthalpy of a thermodynamic system. [2] A typical chart covers a pressure range of 0.01–1000 bar , and temperatures up to 800 degrees Celsius . [ 3 ]
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Thermodynamic databases contain information about thermodynamic properties for substances, the most important being enthalpy, entropy, and Gibbs free energy.Numerical values of these thermodynamic properties are collected as tables or are calculated from thermodynamic datafiles.
The main feature of thermodynamic diagrams is the equivalence between the area in the diagram and energy. When air changes pressure and temperature during a process and prescribes a closed curve within the diagram the area enclosed by this curve is proportional to the energy which has been gained or released by the air.
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It is a useful and common tool, particularly because it helps to visualize the heat transfer during a process. For reversible (ideal) processes, the area under the T–s curve of a process is the heat transferred to the system during that process. [1] Working fluids are often categorized on the basis of the shape of their T–s diagram.
J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.3, Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements and Inorganic Compounds
Table of specific heat capacities at 25 °C (298 K) unless otherwise noted. [citation needed] Notable minima and maxima are shown in maroon. Substance Phase Isobaric mass heat capacity c P J⋅g −1 ⋅K −1 Molar heat capacity, C P,m and C V,m J⋅mol −1 ⋅K −1 Isobaric volumetric heat capacity C P,v J⋅cm −3 ⋅K −1 Isochoric ...