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A lithium-ion or Li-ion battery is a type of rechargeable battery that uses the reversible intercalation of Li + ions into electronically conducting solids to store energy. In comparison with other commercial rechargeable batteries, Li-ion batteries are characterized by higher specific energy, higher energy density, higher energy efficiency, a longer cycle life, and a longer calendar life.
Lithium tetrachloroaluminate is used in some lithium batteries. A solution of lithium tetrachloroaluminate in thionyl chloride is the liquid cathode and electrolyte in those baterries, e.g. the lithium-thionyl chloride cell. Another cathode-electrolyte formulation is lithium tetrachloroaluminate + thionyl chloride + sulfur dioxide + bromine.
Depending on the design and chemical compounds used, lithium cells can produce voltages from 1.5 V (comparable to a zinc–carbon or alkaline battery) to about 3.7 V. Disposable primary lithium batteries must be distinguished from secondary lithium-ion or a lithium-polymer, [3] which are rechargeable batteries
3 is a lithium rich layered rocksalt structure that is made of alternating layers of lithium ions and lithium and manganese ions in a 1:2 ratio, similar to the layered structure of LiCoO 2. In the nomenclature of layered compounds it can be written Li(Li 0.33 Mn 0.67)O 2. [7] Although Li 2 MnO
Lithium is a highly reactive alkali metal that is widely used in various industrial applications due to its unique properties. Lithium compounds are formed by combining lithium with other elements, such as oxygen , sulfur , and chlorine , to form different chemical compounds.
Lithium iodide is used as a solid-state electrolyte for high-temperature batteries. It is also the standard electrolyte in artificial pacemakers [6] due to the long cycle life it enables. [7] The solid is used as a phosphor for neutron detection. [8] It is also used, in a complex with Iodine, in the electrolyte of dye-sensitized solar cells.
Schematic of a lithium ion battery. Initially, lithium cobalt oxide was used as the cathode and polyacetylene as the anode. Later in 1985, it was found that using lithium cobalt oxide as the cathode and graphite as the anode produced an excellent secondary battery with enhanced stability, employing the frontier electron theory of Kenichi Fukui. [4]
Prices of lithium-ion batteries have fallen over time. Overall, between 1991 and 2018, prices for all types of lithium-ion cells (in dollars per kWh) fell approximately 97%. [79] Over the same time period, energy density more than tripled. [79] Efforts to increase energy density contributed significantly to cost reduction. [83]