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904L is an austenitic stainless steel.It is softer than 316L, [1] [2] and its molybdenum addition gives it superior resistance to localized attack (pitting and crevice corrosion) by chlorides and greater resistance reducing acids; in particular, its copper addition gives it useful corrosion resistance to all concentrations of sulfuric acid.
Green death is a solution used to test the resistance of metals and alloys to corrosion. It consists of a mixture of sulfuric acid, hydrochloric acid, iron(III) chloride and copper(II) chloride and its boiling point is at approximately 103 °C. Its typical chemical composition is given in the table hereafter: [1] [2] [3] [4]
For example, alloy 020 is designed to be resistant to sulfuric acid, and the DS Incoloy is to be used in heat-treating furnaces with reactive atmospheres and many heat cycles. Incoloy 020 "exhibits excellent corrosion resistance in chemical environments that contain sulfuric acid, chlorides, phosphoric acid and nitric acid." [5]
Oxidation of pyrite in clay formations in contact with concrete – this produces sulfuric acid which reacts with concrete. Bacterial activity in sewers – anaerobic sulfate reduction at work in the organic-rich sludges accumulated under water in the conduits produces hydrogen sulfide gas (H 2 S).
Alloy 20 is an austenitic stainless steel containing less than 50% iron developed for applications involving sulfuric acid.Its corrosion resistance also finds other uses in the chemical, petrochemical, power generation, and plastics industries.
The lead chamber process for sulfuric acid production was abandoned, partly because it could not produce sulfur trioxide or concentrated sulfuric acid directly due to corrosion of the lead, and absorption of NO 2 gas. Until this process was made obsolete by the contact process, oleum had to be obtained through indirect methods. Historically ...
Sulfuric acid is a colorless oily liquid, and has a vapor pressure of <0.001 mmHg at 25 °C and 1 mmHg at 145.8 °C, [16] and 98% sulfuric acid has a vapor pressure of <1 mmHg at 40 °C. [ 17 ] In the solid state, sulfuric acid is a molecular solid that forms monoclinic crystals with nearly trigonal lattice parameters.
Biogenic sulfide corrosion is a bacterially mediated process of forming hydrogen sulfide gas and the subsequent conversion to sulfuric acid that attacks concrete and steel within wastewater environments. The hydrogen sulfide gas is biochemically oxidized in the presence of moisture to form sulfuric acid.