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In organic chemistry, alkylammonium refers to cations of the formula [R 4−n NH n] +, where R = alkyl and 1≤ n ≤ 4. The cations with four alkyl substituents, i.e., [R 4 N] +, are further classified as quaternary ammonium cations and are discussed more thoroughly in the article with that title.
The hydrogen atoms in the ammonium ion can be substituted with an alkyl group or some other organic group to form a substituted ammonium ion (IUPAC nomenclature: aminium ion). Depending on the number of organic groups, the ammonium cation is called a primary , secondary , tertiary , or quaternary .
Quaternary ammonium cation. The R groups may be the same or different alkyl or aryl groups. Also, the R groups may be connected. In organic chemistry, quaternary ammonium cations, also known as quats, are positively-charged polyatomic ions of the structure [NR 4] +, where R is an alkyl group, an aryl group [1] or organyl group.
A cycloalkyl group is derived from a cycloalkane by removal of a hydrogen atom from a ring and has the general formula −C n H 2n−1. [2] Typically an alkyl is a part of a larger molecule. In structural formulae, the symbol R is used to designate a generic (unspecified) alkyl group. The smallest alkyl group is methyl, with the formula −CH 3 ...
It is an organic salt classified as a quaternary ammonium compound. ADBACs have three main categories of use: as a biocide, a cationic surfactant, and a phase transfer agent. [2] ADBACs are a mixture of alkylbenzyldimethylammonium chlorides, in which the alkyl group has various even-numbered alkyl chain lengths.
Ammonium hypoiodites are a class of reactive intermediates used in certain organic oxidation reactions. They consist of either ammonium itself or an alkylammonium with various substituents as cation , paired with a hypoiodite anion as the active oxidant .
The reactivity of a functional group can be modified by other functional groups nearby. Functional group interconversion can be used in retrosynthetic analysis to plan organic synthesis. A functional group is a group of atoms in a molecule with distinctive chemical properties, regardless of the other atoms in the molecule.
N-alkylation is a general and useful route to quaternary ammonium salts from tertiary amines, because overalkylation is not possible. Examples of N-alkylation with alkyl halides are the syntheses of benzylaniline, [5] 1-benzylindole, [6] [7] and azetidine. [8] Another example is found in the derivatization of cyclen. [9]