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In chemical thermodynamics, excess properties are properties of mixtures which quantify the non-ideal behavior of real mixtures. They are defined as the difference between the value of the property in a real mixture and the value that would exist in an ideal solution under the same conditions.
Probabilistic criteria, similar to those used in SA, are used to select the candidates for mutation or combination, and for discarding excess solutions from the pool. Memetic algorithms search for solutions by employing a set of agents that both cooperate and compete in the process; sometimes the agents' strategies involve simulated annealing ...
In thermodynamics, the enthalpy of mixing (also heat of mixing and excess enthalpy) is the enthalpy liberated or absorbed from a substance upon mixing. [1] When a substance or compound is combined with any other substance or compound, the enthalpy of mixing is the consequence of the new interactions between the two substances or compounds. [1]
Water and ethanol always have negative excess volumes when mixed, indicating the partial molar volume of each component is less when mixed than its molar volume when pure. The partial molar volume is broadly understood as the contribution that a component of a mixture makes to the overall volume of the solution. However, there is more to it ...
In most cases solubility decreases with decreasing temperature; in such cases the excess of solute will rapidly separate from the solution as crystals or an amorphous powder. [2] [3] [4] In a few cases the opposite effect occurs. The example of sodium sulfate in water is well-known and this was why it was used in early studies of solubility.
When the surface excess of a component is positive, increasing the chemical potential of that component reduces the surface tension. Next consider the example of water with salt. The water surface is less salty than bulk, so whenever the water's surface area is increased, it is necessary to remove salt molecules from the new surface and push ...
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Overproduction raises issues about the disposal of excess product stocks, which may have a significant environmental impact as well as raising additional waste disposal costs. More raw materials than necessary will have been used in production and, in some production processes, more undesirable pollution may have arisen due to the excess level ...