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For example, ethyl methyl ether (CH 3 OC 2 H 5), diphenylether (C 6 H 5 OC 6 H 5). As for other organic compounds, very common ethers acquired names before rules for nomenclature were formalized. Diethyl ether is simply called ether, but was once called sweet oil of vitriol. Methyl phenyl ether is anisole, because it was originally found in ...
Alternatively, an ether chain can be named as an alkane in which one carbon is replaced by an oxygen, a replacement denoted by the prefix "oxa". For example, CH 3 OCH 2 CH 3 could also be called 2-oxabutane, and an epoxide could be called oxacyclopropane. This method is especially useful when both groups attached to the oxygen atom are complex.
Examples of phenol ethers and their nomenclature. 5-phenoxynonane follows the same naming scheme as 1-phenoxyoctane, due to nonane having more carbons than a benzene ring. When substituents on aromatic rings are present, standard IUPAC nomenclature should be followed when naming aromatic compounds.
For example, using 18-crown-6, potassium acetate is a more powerful nucleophile in organic solvents: [1] [K·(18-crown-6)] + AcO − + C 6 H 5 CH 2 Cl → C 6 H 5 CH 2 OAc + [K·(18-crown-6)] + Cl −. The first electride salt to be examined with X-ray crystallography, [Cs(18-crown-6) 2] + ·e −, was synthesized in 1983. This highly air- and ...
An example of an ether is the solvent diethyl ether. [1] Halogenated ethers differ from other ethers because there are one or more halogen atoms—fluorine, chlorine, bromine, or iodine—as substituents on the carbon groups. . [2] Examples of commonly used halogenated ethers include isoflurane, sevofluorane and desflurane. [3]
The first number in a crown ether's name refers to the number of atoms in the cycle, and the second number refers to the number of those atoms that are oxygen. Crown ethers are much broader than the oligomers of ethylene oxide; an important group are derived from catechol. Crown ethers strongly bind certain cations, forming complexes. The ...
Some sulfides are named by modifying the common name for the corresponding ether. For example, C 6 H 5 SCH 3 is methyl phenyl sulfide, but is more commonly called thioanisole, since its structure is related to that for anisole, C 6 H 5 OCH 3. The modern systematic nomenclature in chemistry for the trival name thioether is sulfane. [2]
Multiplicative nomenclature is to be preferred over simple substitutive if it can be used. This is the nomenclature with an apostrophe after numbers such as 4'; it allows multiple occurrences of the principal characteristic group or compound class to be treated together. Example: 4,4′-sulfanediyldibenzoic acid refers to (COOH-C 6 H 4) 2 S.