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The diffusion coefficient in solids at different temperatures is generally found to be well predicted by the Arrhenius equation: = where D is the diffusion coefficient (in m 2 /s), D 0 is the maximal diffusion coefficient (at infinite temperature; in m 2 /s),
In dilute aqueous solutions the diffusion coefficients of most ions are similar and have values that at room temperature are in the range of (0.6–2) × 10 −9 m 2 /s. For biological molecules the diffusion coefficients normally range from 10 −10 to 10 −11 m 2 /s.
The diffusion coefficient is the coefficient in the Fick's first law = /, where J is the diffusion flux (amount of substance) per unit area per unit time, n (for ideal mixtures) is the concentration, x is the position [length].
The self-diffusion coefficient of water has been experimentally determined with high accuracy and thus serves often as a reference value for measurements on other liquids. The self-diffusion coefficient of neat water is: 2.299·10 −9 m 2 ·s −1 at 25 °C and 1.261·10 −9 m 2 ·s −1 at 4 °C. [2]
D is the diffusion coefficient; μ is the "mobility", or the ratio of the particle's terminal drift velocity to an applied force, μ = v d /F; k B is the Boltzmann constant; T is the absolute temperature. This equation is an early example of a fluctuation-dissipation relation. [7]
Thermal diffusion coefficients vs. temperature, for air at normal pressure The Maxwell–Stefan diffusion (or Stefan–Maxwell diffusion ) is a model for describing diffusion in multicomponent systems.
Thermal diffusivity is a positive coefficient in the heat equation: [5] =. One way to view thermal diffusivity is as the ratio of the time derivative of temperature to its curvature, quantifying the rate at which temperature concavity is "smoothed out". In a substance with high thermal diffusivity, heat moves rapidly through it because the ...
D is the diffusion coefficient that controls the speed of the diffusive process, and is typically expressed in meters squared over second. If the diffusion coefficient D is not constant, but depends on the concentration c (or P in the second case), then one gets the nonlinear diffusion equation.