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Temperature-dependency of the heats of vaporization for water, methanol, benzene, and acetone. In thermodynamics, the enthalpy of vaporization (symbol ∆H vap), also known as the (latent) heat of vaporization or heat of evaporation, is the amount of energy that must be added to a liquid substance to transform a quantity of that substance into a gas.
Latent heat can be understood as hidden energy which is supplied or extracted to change the state of a substance without changing its temperature or pressure. This includes the latent heat of fusion (solid to liquid), the latent heat of vaporization (liquid to gas) and the latent heat of sublimation (solid to gas). [1] [2]
J.A. Dean (ed.), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
L is the latent heat of vaporization at the temperature T, T C is the critical temperature, L 0 is the parameter that is equal to the heat of vaporization at zero temperature (T → 0), tanh is the hyperbolic tangent function. This equation was obtained in 1955 by Yu. I. Shimansky, at first empirically, and later derived theoretically.
Heat capacity, c p: 0.212 J/(mol K) at −200°C Liquid properties Std enthalpy change of formation, Δ f H o liquid: −318.2 kJ/mol Standard molar entropy, S o liquid: 180 J/(mol K) Heat capacity, c p: 2.68 J/(gK) at 20°C-25°C Gas properties Std enthalpy change of formation, Δ f H o gas: −261.1 kJ/mol Standard molar entropy, S o gas: 333 ...
of vaporization, Δ vap H o: 27.530 kJ/mol at 11.85 °C 27.247 kJ/mol at 22.48 °C Std entropy change of vaporization, Δ vap S o: 96.60 J/(mol·K) at 12° Solid properties Std enthalpy change of formation, Δ f H o solid? kJ/mol Standard molar entropy, S o solid? J/(mol K) Heat capacity, c p? J/(mol K) Liquid properties Std enthalpy change of ...
of vaporization, Δ vap H o: 130.05 @ T-Boiling kJ/mol Std entropy change of vaporization, Δ vap S o? J/(mol·K) Solid properties Std enthalpy change of formation, Δ f H o solid: −411.12 kJ/mol [2] Standard molar entropy, S o solid: 72 J/(mol·K) Heat capacity, c p: 50 J/(mol·K) ; 0.853 J/(g·k) [2] Liquid properties Std enthalpy change of ...