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The crude dimethyl sulfide product was purified by distillation and could then be used to produce DMSO. When Gaylord closed its Bogalusa plant in 2010, it changed its process technology to manufacture DMS from methanol and hydrogen sulfide gas via gas phase thioetherification. This is the dominant method used worldwide to make DMS and there are ...
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Dimethyl sulfide (DMS) or methylthiomethane is an organosulfur compound with the formula (CH 3) 2 S. It is the simplest thioether and has a characteristic disagreeable odor. It is a flammable liquid that boils at 37 °C (99 °F).
It is an adduct between borane molecule (BH 3) and dimethyl sulfide molecule (S(CH 3) 2). It is a complexed borane reagent that is used for hydroborations and reductions . The advantages of BMS over other borane reagents, such as borane-tetrahydrofuran , are its increased stability and higher solubility. [ 1 ]
The primary site for ether cleavage is the α-carbon (carbon atom attached to the aromatic ring) of the propyl (linear three carbon) side chain. The following structures do not specify the structure since lignin and its derivatives are complex mixtures: the purpose is to give a general idea of the structure of lignosulfonates.
3D model Interactive image ... Gibbs free energy ... The dimethyl sulfide adduct (BCl 3 SMe 2), which is a solid, is much safer to use, ...
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