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Lithium grease in use. Lithium soap is a soap consisting of a lithium salt of a fatty acid. [1] [2] Sodium-based and potassium-based soaps are used as cleaning agents in domestic and industrial applications, whereas lithium soaps are used as components of lithium grease (white lithium).
Lithium-based grease has a dropping point at 190 to 220 °C (374 to 428 °F). However the maximum usable temperature for lithium-based grease is 120 °C. The amount of grease in a sample can be determined in a laboratory by extraction with a solvent followed by e.g. gravimetric determination.
Lithium 12-hydroxystearate exhibits high oxidation stability and a dropping point up to around 200 °C. Most greases used today in motor vehicles, aircraft, and heavy machinery contain lithium stearates, mainly lithium 12-hydroxystearate. [1] Greases can be made with the addition of several different metallic soaps.
Lithium soap or greases, such as lithium stearate, are insoluble in water and find use in lubricating grease. Calcium and magnesium soaps are most commonly encountered as soap scum but the pure materials have a variety of uses.
Lithium and its compounds have several industrial applications, including heat-resistant glass and ceramics, lithium grease lubricants, flux additives for iron, steel and aluminium production, lithium metal batteries, and lithium-ion batteries. These uses consume more than three-quarters of lithium production.
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The production of lithium grease consumes a significant amount of castor oil. Hydrogenation and saponification of castor oil yields 12-hydroxystearic acid, which is then reacted with lithium hydroxide or lithium carbonate to give high-performance lubricant grease.
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