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Higher quality lignin presents the potential to become a renewable source of aromatic compounds for the chemical industry, with an addressable market of more than $130bn. [ 26 ] Given that it is the most prevalent biopolymer after cellulose , lignin has been investigated as a feedstock for biofuel production and can become a crucial plant ...
The term "lignin characterization" (or "lignin analysis") refers to a group of activities within lignin research aiming at describing the characteristics of a lignin by determination of its most important properties. [1] Most often, this term is used to describe the characterization of technical lignins by means of chemical or thermo-chemical ...
Kraft lignin from black liquor, which is produced in much higher amounts, may be processed into sulfonated lignin. The lignin is first precipitated by acidifying the liquor with CO 2 then washed (other methods for isolation exist). Reaction with sodium sulfite or sodium bisulfite and an aldehyde under a basic environment completes sulfonation.
Polyphenols, such as lignin, are larger molecules (macromolecules). Their upper molecular weight limit is about 800 daltons , which allows for the possibility to rapidly diffuse across cell membranes so that they can reach intracellular sites of action or remain as pigments once the cell senesces .
Chemical structure of lignin, which makes up about 25% of wood dry matter and is responsible for many of its properties. The chemical composition of wood varies from species to species, but is approximately 50% carbon, 42% oxygen, 6% hydrogen, 1% nitrogen, and 1% other elements (mainly calcium, potassium, sodium, magnesium, iron, and manganese ...
It is composed of two kinds of carbohydrate polymers, cellulose and hemicellulose, and an aromatic-rich polymer called lignin. [1] Any biomass rich in cellulose, hemicelluloses, and lignin are commonly referred to as lignocellulosic biomass. [2] Each component has a distinct chemical behavior.
The black liquor is an aqueous solution of lignin residues, hemicellulose, and the inorganic chemicals used in the process. The black liquor comprises 15% solids by weight of which two thirds are organic chemicals and the remainder are inorganic. [3] Normally the organics in black liquor are 40-45% soaps, [4] 35-45% lignin and 10-15% other ...
The percentage of each component varies for each different type of fiber, however, generally, are around 60-80% cellulose, 5–20% lignin, and 20% of moisture, besides hemicellulose and a small percent of residual chemical components. The properties of the fiber change depending on the amount of each component, since the hemicellulose is ...
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