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Glacial acetic acid is used in analytical chemistry for the estimation of weakly alkaline substances such as organic amides. Glacial acetic acid is a much weaker base than water, so the amide behaves as a strong base in this medium. It then can be titrated using a solution in glacial acetic acid of a very strong acid, such as perchloric acid. [52]
Anhydrous acetic acid is known as glacial acetic acid. ... to distinguish it from its solution in water, hydrochloric acid. ... a.k.a. acid anhydride;
Acetic anhydride, or ethanoic anhydride, is the chemical compound with the formula (CH 3 CO) 2 O. Commonly abbreviated Ac 2 O , it is the simplest isolable anhydride of a carboxylic acid and is widely used as a reagent in organic synthesis .
Water: 100.00 0.512 0.00 –1.86 K b & K f [2] Ethyl Acetate: 77.1 [5] Acetic Anhydride: 139.0 [6] Ethylene Dichloride: 1.25 83.5 −35 [7] Acetonitrile: 0.78 81.6 −45 [8] Heptane: 98.4 [9] Isobutanol: 107.7 [10] n-Hexane: 0.66 68.7 [11] n-Butanol: 117.7 [12] Hydrochloric Acid: 84.8 [13] tert-Butanol: 82.5 [14] Chlorobenzene: 131.7 [15] p ...
Acetic acid vapor pressure vs. temperature. ... Vapor-liquid Equilibrium for Acetic acid/Water [3] P = 760 mm Hg BP Temp. °C mole % water liquid vapor 116.5: 2.2:
However, acetic acid is usually also formed as a by-product of the reaction, so that the solvent is ultimately a mixture of methylene chloride, acetic anhydride and acetic acid. A very rare heterogeneous process is the fiber acetate process, which is only used for the production of cellulose triacetate as an end product.
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
A common type of organic acid anhydride is a carboxylic anhydride, where the parent acid is a carboxylic acid, the formula of the anhydride being (RC(O)) 2 O. Symmetrical acid anhydrides of this type are named by replacing the word acid in the name of the parent carboxylic acid by the word anhydride. [2] Thus, (CH 3 CO) 2 O is called acetic ...