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Borate glasses also have major differences in their optical properties. [ 2 ] The single largest use of boron compounds in the world (accounting for half of total global use) is the production of certain types of boron-treated glass fiber for insulating and structural fiberglass . [ 3 ]
At the age of 21, he left Wisconsin to prospect for mineral wealth in the American West, starting in Nevada. [4]In 1872, while contracting to provide firewood to a small borax operation at nearby Columbus Marsh, Smith discovered a rich supply of ulexite at Teels Marsh in Mineral County, Nevada, east of Mono Lake, near the town he would found ten years later, Marietta, Nevada, while looking ...
Trimethyl borate is the organoboron compound with the formula B(OCH 3) 3 and a metal alkoxide. It is a colourless liquid that burns with a green flame. [1] It is an intermediate in the preparation of sodium borohydride and is a popular reagent in organic chemistry. It is a weak Lewis acid (AN = 23, Gutmann-Beckett method). [2]
Unlike silicates, boron minerals never contain boron with coordination number greater than four. A typical motif is exemplified by the tetraborate anions of the common mineral borax, shown at left. The formal negative charge of the tetrahedral borate center is balanced by metal cations in the minerals, such as the sodium (Na +) in borax. [1]
An important synthetic application using such dialkylboranes, such as diethylborane, is the transmetallation of the organoboron compounds to form organozinc compounds. [9] [10] Some diaryl and dialkylboranes are well known. Dimesitylborane is a dimer (C 6 H 2 Me 3) 4 B 2 H 2). It reacts only slowly with simple terminal alkenes.
Lithium metaborate forms glass relatively easily, and consists of approximately 40% tetrahedral borate anions, and 60% trigonal planar boron. The ratio of tetrahedral to trigonal boron has been shown to be strongly temperature dependent in the liquid and supercooled liquid state. [3] [4]
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When the Storey brothers' interests were subsequently acquired in 1873, the name was shortened to Smith Brothers Borax Co. A few years later (circa 1884) it was changed again to Teel's Marsh Borax Co. In 1880, the separate and previously existing Pacific Borax Company (with no "Coast" in the name) was acquired by Smith. Frank Smith also ...