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Borate glasses also have major differences in their optical properties. [ 2 ] The single largest use of boron compounds in the world (accounting for half of total global use) is the production of certain types of boron-treated glass fiber for insulating and structural fiberglass . [ 3 ]
Unlike silicates, boron minerals never contain boron with coordination number greater than four. A typical motif is exemplified by the tetraborate anions of the common mineral borax, shown at left. The formal negative charge of the tetrahedral borate center is balanced by metal cations in the minerals, such as the sodium (Na +) in borax. [1]
Lithium metaborate forms glass relatively easily, and consists of approximately 40% tetrahedral borate anions, and 60% trigonal planar boron. The ratio of tetrahedral to trigonal boron has been shown to be strongly temperature dependent in the liquid and supercooled liquid state. [3] [4]
Many sodium borates have important industrial and household applications; the best known being borax, (Na +) 2 [B 4 O 5 (OH) 4] 2− ·8H 2 O = Na 2 B 4 H 20 O 17. The ternary phase diagram of the Na 2 O – B 2 O 3 – H 2 O phase diagram in the 0–100 °C temperature range contains 13 unique hydrated crystalline sodium borates, including ...
Trimethyl borate is the organoboron compound with the formula B(OCH 3) 3 and a metal alkoxide. It is a colourless liquid that burns with a green flame. [1] It is an intermediate in the preparation of sodium borohydride and is a popular reagent in organic chemistry. It is a weak Lewis acid (AN = 23, Gutmann-Beckett method). [2]
An important synthetic application using such dialkylboranes, such as diethylborane, is the transmetallation of the organoboron compounds to form organozinc compounds. [9] [10] Some diaryl and dialkylboranes are well known. Dimesitylborane is a dimer (C 6 H 2 Me 3) 4 B 2 H 2). It reacts only slowly with simple terminal alkenes.
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Zinc borate refers to a family of inorganic compounds consisting of borate of zinc.They are white solids with the formulas 4ZnO·B 2 O 3 ·H 2 O, ZnO·B 2 O 3 ·1.12H 2 O, ZnO·B 2 O 3 ·∼2H 2 O, 6ZnO·5B 2 O 3 ·3H 2 O, 2ZnO·3B 2 O 3 ·7H 2 O, 2ZnO·3B 2 O 3 ·3H 2 O, 3ZnO·5B 2 O 3 ·14H 2 O, and ZnO·5B 2 O 3 ·4.5H 2 O.