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The simplest definition for a potential gradient F in one dimension is the following: [1] = = where ϕ(x) is some type of scalar potential and x is displacement (not distance) in the x direction, the subscripts label two different positions x 1, x 2, and potentials at those points, ϕ 1 = ϕ(x 1), ϕ 2 = ϕ(x 2).
The concept of potential temperature applies to any stratified fluid. It is most frequently used in the atmospheric sciences and oceanography. [2] The reason that it is used in both fields is that changes in pressure can result in warmer fluid residing under colder fluid – examples being dropping air temperature with altitude and increasing water temperature with depth in very deep ocean ...
If ϕ is a velocity potential, then ϕ + f(t) is also a velocity potential for u, where f(t) is a scalar function of time and can be constant. Velocity potentials are unique up to a constant, or a function solely of the temporal variable. The Laplacian of a velocity potential is equal to the divergence of the corresponding flow.
The gradient of F is then normal to the hypersurface. Similarly, an affine algebraic hypersurface may be defined by an equation F(x 1, ..., x n) = 0, where F is a polynomial. The gradient of F is zero at a singular point of the hypersurface (this is the definition of a singular point). At a non-singular point, it is a nonzero normal vector.
By placing φ as potential, ∇φ is a conservative field. Work done by conservative forces does not depend on the path followed by the object, but only the end points, as the above equation shows. The gradient theorem also has an interesting converse: any path-independent vector field can be expressed as the gradient of a scalar field. Just ...
The Tafel equation was first deduced experimentally and was later shown to have a theoretical justification. The equation is named after Swiss chemist Julius Tafel . It describes how the electrical current through an electrode depends on the voltage difference between the electrode and the bulk electrolyte for a simple, unimolecular redox reaction.
The discharge potential is a potential in groundwater mechanics which links the physical properties, hydraulic head, with a mathematical formulation for the energy as a function of position. The discharge potential, Φ {\textstyle \Phi } [L 3 ·T −1 ], is defined in such way that its gradient equals the discharge vector.
In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing ...