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Lithium cyanide is an inorganic compound with the chemical formula LiCN. It is a toxic, white coloured, hygroscopic , water-soluble salt that finds only niche uses. Preparation
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Lithium thiocyanate is a chemical compound with the formula LiSCN. It is an extremely hygroscopic white solid that forms the monohydrate and the dihydrate. It is the least stable of the alkali metal thiocyanates due to the large electrostatic deforming field of the lithium cation.
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The lithium, sodium, and potassium salts are prepared by reduction of chlorodiphenylphosphine, [1] triphenylphosphine, [2] [3] or tetraphenyldiphosphine with alkali metals (M):
Lithium cyclopentadienide is commercially available as a solution in tetrahydrofuran.It is prepared by treating cyclopentadiene with butyllithium: [1]. C 5 H 6 + LiC 4 H 9 → LiC 5 H 5 + C 4 H 10
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Lithium amide or lithium azanide is an inorganic compound with the chemical formula LiNH 2.It is a white solid with a tetragonal crystal structure. [1] Lithium amide can be made by treating lithium metal with liquid ammonia: [2]