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A fullerene is an allotrope of carbon whose molecules consist of carbon atoms connected by ... D. A. Bochvar and E. G. Galpern made a quantum-chemical analysis of the ...
Fullerene chemistry is a field of organic chemistry devoted to the chemical properties of fullerenes. [1] [2] [3] Research in this field is driven by the need to functionalize fullerenes and tune their properties. For example, fullerene is notoriously insoluble and adding a suitable group can enhance solubility. [1]
PCBM ([6,6]-phenyl-C 61-butyric acid methyl ester) is a fullerene derivative being investigated for its potential use in organic solar cells. [3]PCBM is a fullerene derivative of the C 60 buckyball that was first synthesized in the 1990s. [4]
Polyfullerene is a basic polymer of the C 60 monomer group, in which fullerene segments are connected via covalent bonds into a polymeric chain without side or bridging groups. They are called intrinsic polymeric fullerenes, or more often all C 60 polymers. Fullerene can be part of a polymer chain in many different ways.
A transition metal fullerene complex is a coordination complex wherein fullerene serves as a ligand. Fullerenes are typically spheroidal carbon compounds, the most prevalent being buckminsterfullerene, C 60. [2] One year after it was prepared in milligram quantities in 1990, [3] C 60 was shown to function as a ligand in the complex [Ph 3 P] 2 ...
Alternatively, endohedral hydrogen fullerenes can be produced by opening and closing a fullerene by organic chemistry methods. A recent example of endohedral fullerenes includes single molecules of water encapsulated in C 60. [10] Noble gas endofullerenes are predicted to exhibit unusual polarizability.
Fullerene whiskers and tubes are held together by weak van der Waals forces, and hence are very soft. [1] They can be grown by precipitation at an interface between two liquids. They are semiconductors and have potential uses in field-effect transistors , solar cells , chemical sensors, and photocatalysts .
Heterofullerenes are classes of fullerenes, at least one carbon atom is replaced by another element. [1] [2] Based on spectroscopy, substitutions have been reported with boron (borafullerenes), [3] [4] nitrogen (azafullerenes), [5] [6] oxygen, [7] arsenic, germanium, [8] phosphorus, [9] silicon, [10] [11] iron, copper, nickel, rhodium [11] [12] and iridium. [11]
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