Search results
Results from the WOW.Com Content Network
Oleylamine is an organic compound with a molecular formula C 18 H 35 NH 2. [1] It is an unsaturated fatty amine related to the fatty acid oleic acid.The pure compound is a clear and colorless liquid.
This article about a hydrocarbon is a stub. You can help Wikipedia by expanding it.
Schiff bases can be synthesized from an aliphatic or aromatic amine and a carbonyl compound by nucleophilic addition forming a hemiaminal, followed by a dehydration to generate an imine.
In the empirical sciences, the so-called three-sigma rule of thumb (or 3 σ rule) expresses a conventional heuristic that nearly all values are taken to lie within three standard deviations of the mean, and thus it is empirically useful to treat 99.7% probability as near certainty.
According to the sigma bond rule, the number of sigma bonds in a molecule is equivalent to the number of atoms plus the number of rings minus one. N σ = N atoms + N rings − 1 This rule is a special-case application of the Euler characteristic of the graph which represents the molecule.
Hyperconjugation affects several properties. [6] [10]Bond length: Hyperconjugation is suggested as a key factor in shortening of sigma bonds (σ bonds). For example, the single C–C bonds in 1,3-butadiene and propyne are approximately 1.46 Å in length, much less than the value of around 1.54 Å found in saturated hydrocarbons.
In organic chemistry, a sigmatropic reaction (from Greek τρόπος (trópos) 'turn') is a pericyclic reaction wherein the net result is one sigma bond (σ-bond) is changed to another σ-bond in an intramolecular reaction. [1]
Tautomers of a substituted HNacNac ligand precursor and an idealized complex (right) of the conjugate base (M = metal, L = other ligand). NacNac is a class of anionic bidentate ligands. 1,3-Diketimines are often referred to as "HNacNac", a modification of the abbreviation Hacac used for 1,3-diketones.