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Relative humidity is defined relative to saturation vapor pressure. [18] Equilibrium vapor pressure does not require the condensed phase to be a flat surface; it might consist of tiny droplets possibly containing solutes (impurities), such as a cloud.
There are several empirical formulas that can be used to estimate the equilibrium vapor pressure of water vapor as a function of temperature. The Antoine equation is among the least complex of these, having only three parameters ( A , B , and C ).
The definition of a w is where p is the partial water vapor pressure in equilibrium with the solution, and p* is the (partial) vapor pressure of pure water at the same temperature. An alternate definition can be a w ≡ l w x w {\displaystyle a_{w}\equiv l_{w}x_{w}} where l w is the activity coefficient of water and x w is the mole fraction of ...
Atmospheric thermodynamics is the study of heat-to-work transformations (and their reverse) that take place in the Earth's atmosphere and manifest as weather or climate. . Atmospheric thermodynamics use the laws of classical thermodynamics, to describe and explain such phenomena as the properties of moist air, the formation of clouds, atmospheric convection, boundary layer meteorology, and ...
The vapor pressure of water is the pressure exerted by molecules of water vapor in gaseous form (whether pure or in a mixture with other gases such as air). The saturation vapor pressure is the pressure at which water vapor is in thermodynamic equilibrium with its condensed state .
The concentration of a vapor in contact with its liquid, especially at equilibrium, is often expressed in terms of vapor pressure, which will be a partial pressure (a part of the total gas pressure) if any other gas(es) are present with the vapor. The equilibrium vapor pressure of a liquid is in general strongly dependent on temperature. At ...
The relation of equilibrium vapor pressure to the saturation vapor pressure can be thought of as a relative humidity measurement for the atmosphere. As P v /P sat increases, vapor will continue to condense inside a given capillary. If P v /P sat decreases, liquid will begin to evaporate into the atmosphere as vapor molecules. [2]
Köhler theory combines the Kelvin effect, which describes the change in vapor pressure due to a curved surface, with Raoult's Law, which relates the vapor pressure to the solute concentration. [ 1 ] [ 2 ] [ 3 ] It was initially published in 1936 by Hilding Köhler , Professor of Meteorology in the Uppsala University.