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The Wohlwill process is an industrial-scale chemical procedure used to refine gold to the highest degree of purity (99.999%). [1] The process was invented in 1874 by Emil Wohlwill . This electrochemical process involves using a cast gold ingot , often called a doré bar , of 95%+ gold to serve as an anode .
The Miller process affords gold up to 99.5% purity. The process involves blowing a stream of chlorine through molten gold. Impurities in the gold form chlorides, which form a slag that floats on the molten gold. [2] [3] Invented by Emil Wohlwill in 1874, the Wohlwill process produces the highest purity gold (99.999%). It is an electrolytic ...
Alternative methods exist for parting gold. Silver can be dissolved selectively by boiling the mixture with 30% nitric acid, a process sometimes called inquartation. Affination is a largely obsolete process of removing silver from gold using concentrated sulfuric acid. [8] Electrolysis using the Wohlwill process is yet another approach.
The resulting gold is 99.5% pure, but of lower purity than gold produced by the other common refining method, the Wohlwill process, which produces gold of up to 99.999% purity. [1] [2] The Wohlwill process is commonly used for producing high-purity gold, such as in electronics work, where exacting standards of purity are required.
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Wolf Emil Wohlwill (24 November 1835 in Seesen – 2 February 1912 in Hamburg) was a German-Jewish engineer of electrochemistry. He invented the Wohlwill process in 1874. Literary works
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