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The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.
Exponential functions occur very often in solutions of differential equations. The exponential functions can be defined as solutions of differential equations. Indeed, the exponential function is a solution of the simplest possible differential equation, namely ′ = .
In combinatorial mathematics, the exponential formula (called the polymer expansion in physics) states that the exponential generating function for structures on finite sets is the exponential of the exponential generating function for connected structures. The exponential formula is a power series version of a special case of Faà di Bruno's ...
In mathematics, the exponential function can be characterized in many ways. This article presents some common characterizations, discusses why each makes sense, and proves that they are all equivalent. The exponential function occurs naturally in many branches of mathematics. Walter Rudin called it "the most important function in mathematics". [1]
The number e is a mathematical constant approximately equal to 2.71828 that is the base of the natural logarithm and exponential function.It is sometimes called Euler's number, after the Swiss mathematician Leonhard Euler, though this can invite confusion with Euler numbers, or with Euler's constant, a different constant typically denoted .
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
In the equation, k B and h are the Boltzmann and Planck constants, respectively. Although the equations look similar, it is important to note that the Gibbs energy contains an entropic term in addition to the enthalpic one. In the Arrhenius equation, this entropic term is accounted for by the pre-exponential factor A.
In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing ...
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