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This space-dependence is called a normal mode. Usually, for problems with continuous dependence on (x, y, z) there is no single or finite number of normal modes, but there are infinitely many normal modes. If the problem is bounded (i.e. it is defined on a finite section of space) there are countably many normal modes (usually numbered n = 1, 2 ...
The GF method, sometimes referred to as FG method, is a classical mechanical method introduced by Edgar Bright Wilson to obtain certain internal coordinates for a vibrating semi-rigid molecule, the so-called normal coordinates Q k. Normal coordinates decouple the classical vibrational motions of the molecule and thus give an easy route to ...
Normal coordinates exist on a normal neighborhood of a point p in M. A normal neighborhood U is an open subset of M such that there is a proper neighborhood V of the origin in the tangent space T p M, and exp p acts as a diffeomorphism between U and V. On a normal neighborhood U of p in M, the chart is given by: :=: The isomorphism E, and ...
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
An orthonormal inertial frame is a coordinate chart such that, at the origin, one has the relations = and = (but these may not hold at other points in the frame). These coordinates are also called normal coordinates.
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A logical choice of generalized coordinates to describe the motion are the angles (θ, φ). Only two coordinates are needed instead of three, because the position of the bob can be parameterized by two numbers, and the constraint equation connects the three coordinates (x, y, z) so any one of them is determined from the other two.
The Hamiltonian of the particle is: ^ = ^ + ^ = ^ + ^, where m is the particle's mass, k is the force constant, = / is the angular frequency of the oscillator, ^ is the position operator (given by x in the coordinate basis), and ^ is the momentum operator (given by ^ = / in the coordinate basis).