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Biphenyl (also known as diphenyl, phenylbenzene, 1,1′-biphenyl, lemonene [4] or BP) is an organic compound that forms colorless crystals. Particularly in older literature, compounds containing the functional group consisting of biphenyl less one hydrogen (the site at which it is attached) may use the prefixes xenyl or diphenylyl .
Biphenylene was first synthesized by Lothrop in 1941. [12] The biphenylene structure can also be understood as a dimer of the reactive intermediate benzyne, which in fact serves as a major synthetic route, by heating the benzenediazonium-2-carboxylate zwitterion prepared from 2-aminobenzoic acid. [13]
The industrial synthesis of 4,4′-biphenol was developed by Allan Hay in the 1960s. [ 2 ] [ 3 ] As the direct oxidative coupling of phenol gives a mixture of isomers, [ 4 ] [ 5 ] 4,4′-biphenol is instead prepared from 2,6-di-tert-butylphenol , where para-coupling is the only possibility. [ 3 ]
Dihydroxybiphenyl (as known as biphenol) refers to a class of organic compounds consisting of a biphenyl structure with two hydroxyl groups attached. The most common isomers are 2,2'-dihydroxybiphenyl and 4,4'-dihydroxybiphenyl.
The synthesis of BPA still follows Dianin's general method, with the fundamentals changing little in 130 years. The condensation of acetone (hence the suffix 'A' in the name) [ 33 ] with two equivalents of phenol is catalyzed by a strong acid, such as concentrated hydrochloric acid , sulfuric acid , or a solid acid resin such as the sulfonic ...
In organic chemistry, the phenyl group, or phenyl ring, is a cyclic group of atoms with the formula C6H5, and is often represented by the symbol Ph (archaically φ) or Ø. The phenyl group is closely related to benzene and can be viewed as a benzene ring, minus a hydrogen, which may be replaced by some other element or compound to serve as a ...
The coplanar group members have a fairly rigid structure, with their two phenyl rings in the same plane. It renders their structure similar to polychlorinated dibenzo- p -dioxins (PCDDs) and polychlorinated dibenzofurans , and allows them to act like PCDDs, as an agonist of the aryl hydrocarbon receptor (AhR) in organisms.
In enzymology, a biphenyl synthase (EC 2.3.1.177) is an enzyme that catalyzes the chemical reaction: . 3 malonyl-CoA + benzoyl-CoA 4 CoA + 3,5-dihydroxybiphenyl + 4 CO 2. Thus, the two substrates of this enzyme are malonyl-CoA and benzoyl-CoA, whereas its three products are CoA, 3,5-dihydroxybiphenyl, and CO 2.