Search results
Results from the WOW.Com Content Network
The electron affinity of molecules is a complicated function of their electronic structure. For instance the electron affinity for benzene is negative, as is that of naphthalene, while those of anthracene, phenanthrene and pyrene are positive. In silico experiments show that the electron affinity of hexacyanobenzene surpasses that of fullerene. [5]
Ionization energies calculated from DFT orbital energies are usually poorer than those of Koopmans' theorem, with errors much larger than two electron volts possible depending on the exchange-correlation approximation employed. [3] [4] The LUMO energy shows little correlation with the electron affinity with typical approximations. [9]
Electron affinity can be defined in two equivalent ways. First, as the energy that is released by adding an electron to an isolated gaseous atom. The second (reverse) definition is that electron affinity is the energy required to remove an electron from a singly charged gaseous negative ion.
One component is the difference in the work function (also called the electron affinity) between the two materials. [48] This can lead to charge transfer as, for instance, analyzed by Harper. [ 49 ] [ 50 ] As has been known since at least 1953, [ 37 ] [ 51 ] [ 52 ] [ 53 ] the contact potential is part of the process but does not explain many ...
The electron affinity (usually given by the symbol in solid state physics) gives the energy difference between the lower edge of the conduction band and the vacuum level of the semiconductor. The band gap (usually given the symbol E g {\displaystyle E_{\rm {g}}} ) gives the energy difference between the lower edge of the conduction band and the ...
The hydrogen anion, H −, is a negative ion of hydrogen, that is, a hydrogen atom that has captured an extra electron. The hydrogen anion is an important constituent of the atmosphere of stars, such as the Sun. In chemistry, this ion is called hydride. The ion has two electrons bound by the electromagnetic force to a nucleus containing one proton.
Get AOL Mail for FREE! Manage your email like never before with travel, photo & document views. Personalize your inbox with themes & tabs. You've Got Mail!
The wider the electron shells are in space, the weaker is the electric interaction between the electrons and the nucleus due to screening. Further, because of differences in orbital penetration, we can order the screening strength, S, that electrons in a given orbital (s, p, d, or f) provide to the rest of the electrons thusly: > > > ().