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In materials science, an intrinsic property is independent of how much of a material is present and is independent of the form of the material, e.g., one large piece or a collection of small particles. Intrinsic properties are dependent mainly on the fundamental chemical composition and structure of the material. [1]
Extrinsic means that the chirality is a consequence of the arrangement of different components, rather than an intrinsic property of the components themself. For example, the propagation direction of a beam of light through an achiral crystal (or metamaterial) can form an experimental arrangement that is different from its mirror image.
It is an intrinsic property of a substance that is caused by the shape and structure of its molecules, which makes the distribution of surrounding electrons irregular when molecules get close to one another, creating electrical attraction that can maintain a macroscopic structure such as a water drop.
In chemistry, inherent chirality is a property of asymmetry in molecules arising, not from a stereogenic or chiral center, but from a twisting of the molecule in 3-D space. The term was first coined by Volker Boehmer in a 1994 review, to describe the chirality of calixarenes arising from their non-planar structure in 3-D space.
An intrinsic property is a property that a thing has itself, including its context. An extrinsic (or relational ) property is a property that depends on a thing's relationship with other things. For example, mass is an intrinsic property of any physical object , whereas weight is an extrinsic property that varies depending on the strength of ...
The symmetry properties of crystal are described by the concept of space groups. [1] All possible symmetric arrangements of particles in three-dimensional space may be described by 230 space groups. The crystal structure and symmetry play a critical role in determining many physical properties, such as cleavage , electronic band structure , and ...
Suppose a composite property is a function of a set of intensive properties {} and a set of extensive properties {}, which can be shown as ({}, {}). If the size of the system is changed by some scaling factor, λ {\displaystyle \lambda } , only the extensive properties will change, since intensive properties are independent of the size of the ...
Intrinsic bond orbitals (IBO) are localized molecular orbitals giving exact and non-empirical representations of wave functions. They are obtained by unitary transformation and form an orthogonal set of orbitals localized on a minimal number of atoms.