Search results
Results from the WOW.Com Content Network
Compressing aluminium sulfide to 2–65 bar results in the δ phase where vacancies are arranged in a superlattice of tetragonal symmetry. [ 5 ] Unlike Al 2 O 3 , in which the Al(III) centers occupy octahedral holes, the more expanded framework of Al 2 S 3 stabilizes the Al(III) centers into one third of the tetrahedral holes of a hexagonally ...
The only stable chalcogenides under normal conditions are aluminium sulfide (Al 2 S 3), selenide (Al 2 Se 3), and telluride (Al 2 Te 3). All three are prepared by direct reaction of their elements at about 1,000 °C (1,832 °F) and quickly hydrolyse completely in water to yield aluminium hydroxide and the respective hydrogen chalcogenide.
Aluminium carbide – Al 4 C 3 [12] Aluminium iodide – AlI 3 [13] Aluminium nitride – AlN [14] Aluminium oxide – Al 2 O 3 [15] Aluminium phosphide – AlP [16] Aluminium chloride – AlCl 3 [17] Aluminium fluoride – AlF 3 [18] Aluminium hydroxide – Al(OH) 3 [19] [20] Aluminium nitrate – Al(NO 3) 3 [21] Aluminium sulfide – Al 2 S 3 ...
Organoaluminium compounds generally feature three- and four-coordinate Al centers, although higher coordination numbers are observed with inorganic ligands such as fluoride. In accord with the usual trends, four-coordinate Al prefers to be tetrahedral. In contrast to boron, aluminium is a larger atom and easily accommodates four carbon ligands.
A compound semiconductor is a semiconductor compound composed of chemical elements of at least two different species. These semiconductors form for example in periodic table groups 13–15 (old groups III–V), for example of elements from the Boron group (old group III, boron, aluminium, gallium, indium) and from group 15 (old group V, nitrogen, phosphorus, arsenic, antimony, bismuth).
As aluminium is a small atom relative to these chalcogens, these have four-coordinate tetrahedral aluminium with various polymorphs having structures related to wurtzite, with two-thirds of the possible metal sites occupied either in an orderly (α) or random (β) fashion; the sulfide also has a γ form related to γ-alumina, and an unusual ...
It is known that aluminum improves the sulfidation resistance of iron alloys. [2] The sulfidation of tungsten is a multiple step process. The first step is an oxidation reaction, converting the tungsten to a tungsten bronze on the surface of the object. The tungsten bronze coating is then converted to a sulfide. [3]
This page was last edited on 16 November 2024, at 12:16 (UTC).; Text is available under the Creative Commons Attribution-ShareAlike 4.0 License; additional terms may apply.