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Inverse spinel structures have a different cation distribution in that all of the A cations and half of the B cations occupy octahedral sites, while the other half of the B cations occupy tetrahedral sites. An example of an inverse spinel is Fe 3 O 4, if the Fe 2+ (A 2+) ions are d 6 high-spin and the Fe 3+ (B 3+) ions are d 5 high-spin.
Polyhedral representation of spinel MgAl 2 O 4. Spinel (/ s p ɪ ˈ n ɛ l, ˈ s p ɪ n əl / [7]) is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula MgAl 2 O 4 in the cubic crystal system. Its name comes from the Latin word spinella, a diminutive form of spine, in reference to its pointed crystals. [5]
The mineral ceylonite has the chemical composition of (Mg, Fe 2+) Al 2 O 4, putting it into a group of minerals known as the spinel group, or the oxide spinels. The oxide spinels have a formula of the model [A][B] 2 O 4; where [A] is commonly Fe 2+, Mg 2+, or Mn 2+, and [B] is Fe 3+, Al 3+, or Cr 3+. It is an iron-rich variety of the spinel ...
Ringwoodite is polymorphous with forsterite, Mg 2 SiO 4, and has a spinel structure.Spinel group minerals crystallize in the isometric system with an octahedral habit. Olivine is most abundant in the upper mantle, above about 410 km (250 mi); the olivine polymorphs wadsleyite and ringwoodite are thought to dominate the transition zone of the mantle, a zone present from about 410 to 660 km
Samarian Spinel, the world's largest spinel; Menshikov Ruby, the world's second largest spinel set on top of the Great Imperial Crown of Russia; Timur Ruby, believed to be a ruby until 1851, hence its name; Black Prince's Ruby, the famous spinel mounted on the Imperial State Crown of the United Kingdom
In 2016, jeweler Olivia Young of Ouroboros sold a red spinel ring for £6,000 ($7,700). Last year, the client’s insurance company paid out £30,000 ($38,400) to replace it.
The gemstone at the front of the Imperial State Crown. The Black Prince's Ruby is a large, irregular cabochon red spinel weighing 170 carats (34 g) set in the cross pattée above the Cullinan II diamond at the front of the Imperial State Crown of the United Kingdom. [1]
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