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John Roebuck of Kinneil FRS FRSE (1718 – 17 July 1794) was an English industrialist, inventor, mechanical engineer, and physician who played an important role in the Industrial Revolution and who is known for developing the industrial-scale manufacture of sulfuric acid.
The lead chamber process was an industrial method used to produce sulfuric acid in large quantities. It has been largely supplanted by the contact process.. In 1746 in Birmingham, England, John Roebuck began producing sulfuric acid in lead-lined chambers, which were stronger and less expensive and could be made much larger than the glass containers that had been used previously.
Although nearly 100% sulfuric acid solutions can be made, the subsequent loss of SO 3 at the boiling point brings the concentration to 98.3% acid. The 98.3% grade, which is more stable in storage, is the usual form of what is described as "concentrated sulfuric acid".
What made the 1948 event more severe was ... The sulfuric acid, nitrogen ... Lynne Page. "'The death-dealing smog over Donora, Pennsylvania': industrial air pollution ...
1650 – Turquet de Mayerne obtains a gas or "inflammable air" by the action of dilute sulphuric acid on iron. 1662 – Boyle's law (gas law relating pressure and volume). 1670 – Robert Boyle produces hydrogen by reacting metals with acid. 1672 – "New Experiments touching the Relation between Flame and Air" by Robert Boyle.
The hydrogen sulfide can be used as a sulfur source for the lead chamber process to produce the sulfuric acid used in the first step of the Leblanc process. Likewise, by 1874 the Deacon process was invented, oxidizing the hydrochloric acid over a copper catalyst: 4 HCl(g) + O_ 2 (g) → H 2 O(g) + Cl 2 (g)
The contact process is a method of producing sulfuric acid in the high concentrations needed for industrial processes. Platinum was originally used as the catalyst for this reaction; however, because it is susceptible to reacting with arsenic impurities in the sulfur feedstock, vanadium(V) oxide (V 2 O 5) has since been preferred.
It could then be sold to the sulfuric acid works for a small profit. Lime was sometimes still used after the iron ore had thoroughly removed the sulfuret of hydrogen, to remove carbonic acid (carbon dioxide, CO 2), the bisulfuret of carbon (carbon disulfide, CS 2), and any ammonia still aeroform after its travels through the works. But it was ...