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In chemical nomenclature, the IUPAC nomenclature of organic chemistry is a method of naming organic chemical compounds as recommended [1] [2] by the International Union of Pure and Applied Chemistry (IUPAC). It is published in the Nomenclature of Organic Chemistry (informally called the Blue Book). [3]
IUPAC states that, "As one of its major activities, IUPAC develops Recommendations to establish unambiguous, uniform, and consistent nomenclature and terminology for specific scientific fields, usually presented as: glossaries of terms for specific chemical disciplines; definitions of terms relating to a group of properties; nomenclature of chemical compounds and their classes; terminology ...
The IUPAC's rules for naming organic and inorganic compounds are contained in two publications, known as the Blue Book [1] [2] and the Red Book, [3] respectively. A third publication, known as the Green Book , [ 4 ] recommends the use of symbols for physical quantities (in association with the IUPAP ), while a fourth, the Gold Book , [ 5 ...
In the example, there is a bromo-substituted -CH 2-CH 2 - subunit. 1-Bromoethane-1,2-diyl is chosen in preference to 2- bromoethane-1,2-diyl as the former has a lower locant for the bromo-substituent. The preferred CRU is therefore oxy(1-bromoethane-1,2-diyl) and the polymer is thus named poly[oxy(1-bromoethane-1,2-diyl)].
There are a number of exceptions and special cases that violate the above rules. Sometimes the prefix is left off the initial atom: I 2 O 5 is known as iodine pentaoxide, but it should be called diiodine pentaoxide. N 2 O 3 is called nitrogen sesquioxide (sesqui-means 1 + 1 ⁄ 2). The main oxide of phosphorus is called phosphorus pentaoxide.
In the ICZN, the system is also called binominal nomenclature, [1] "binomi'N'al" with an "N" before the "al", which is not a typographic error, meaning "two-name naming system". [ 2 ] The first part of the name – the generic name – identifies the genus to which the species belongs, whereas the second part – the specific name or specific ...
decacarbonyl-1κ 3 C,2κ 3 C,3κ 4 C-di-μ-hydrido-1:2κ 2 H;1:2κ 2 H-triangulo-(3 Os—Os), (Decacarbonyldihydridotriosmium). decacarbonyl-1κ 3 C,2κ 3 C,3κ 4 C shows that there are three carbonyl groups on two osmium atoms and four on the third. di-μ-hydrido-1:2κ 2 H;1:2κ 2 H specifies that the two hydride bridge between the osmium atom ...
If they are used at all, context should clarify (disambiguate) into the 1–18 numbering. Care should be taken when translating old sources that use this nomenclature to modern terminology. Some sets of groups have names: The main group elements are the elements of groups 1, 2, and 13–18 (i.e. the s-block and p-block). [5]