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Byakuya uses his bankai and overwhelms Ichigo with millions of tiny blades. In response, Ichigo uses his own bankai, which makes him incredibly fast. Ichigo evades Byakuya's bankai and stabs him with his sword. Meanwhile, Tōshirō Hitsugaya and Rangiku Matsumoto head to the Central 46 Chambers, the highest authority in the Soul Society.
Yoruichi Shihōin is a woman who has an ability where she can transform into a black cat for long periods of time. She is intelligent and witty, and is intimately knowledgeable of Soul Society and its workings, as she was the former leader of the Stealth Forces and the 2nd division captain.
As Ichigo deals with Gin and his bankai Kamishini no Yari, Isshin faces Aizen as the latter begins to transform while explaining that the Hōgyoku's true power is granting the wish of its possessor. Even with Urahara and Yoruichi joining Isshin, their efforts are ineffective as Aizen continues to slowly evolve.
Yoruichi Shihōin (四楓院 夜一, Shihōin Yoruichi) is an old friend of Urahara Shop owner Kisuke Urahara, and so uses it as a place of residence when she is not abroad. [17] She is a slim, dark-skinned woman with deep-violet hair.
Yoruichi discusses with Ukitake, Kyōraku and Kenpachi on how they are going to rescue Yamamoto, knowing that they will be running into high-class zanpakutō. Meanwhile, Kazeshini comes back to the hideout and faints from exhaustion. Ukitake, Kyōraku and Kenpachi head into the cave in one direction, and Yoruichi and Ichigo head in another way.
Though Ichigo arrives to face Byakuya, Yoruichi knocks Ichigo out and spirits him away. After Ichigo regains consciousness, Yoruichi tells him that she will train him to use his zanpakutō's bankai state. Meanwhile, on their way to Rukia, Orihime and Uryū are attacked by Squad 12's Captain Mayuri Kurotsuchi.
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Uryū confronts the mysterious scientist while Ichigo, Rukia, and Yoruichi plan their escape from the Soul Society, assuming that several reigai have blocked the Senkaimon, the gateway to the Dangai. Uryū is defeated by the scientist's shikai of his zanpakutō, Raikū. Yoruichi fights the reigai to let Ichigo and Rukia escape.