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In chemistry, a counterion (sometimes written as "counter ion", pronounced as such) is the ion that accompanies an ionic species in order to maintain electric neutrality. In table salt (NaCl, also known as sodium chloride) the sodium ion (positively charged) is the counterion for the chloride ion (negatively charged) and vice versa.
Each ion can be either monatomic (termed simple ion), such as sodium (Na +) and chloride (Cl −) in sodium chloride, or polyatomic, such as ammonium (NH + 4) and carbonate (CO 2− 3) ions in ammonium carbonate. Salts containing basic ions hydroxide (OH −) or oxide (O 2−) are classified as bases, such as sodium hydroxide and potassium oxide.
Sodium chloride / ˌ s oʊ d i ə m ˈ k l ɔːr aɪ d /, [8] commonly known as edible salt, is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chlorine ions. It is transparent or translucent, brittle, hygroscopic , and occurs as the mineral halite .
The practical importance of high (i.e. close to 1) transference numbers of the charge-shuttling ion (i.e. Li+ in lithium-ion batteries) is related to the fact, that in single-ion devices (such as lithium-ion batteries) electrolytes with the transfer number of the ion near 1, concentration gradients do not develop. A constant electrolyte ...
Atomic numbers (Z) are a special case of charge numbers, referring to the charge number of an atomic nucleus, as opposed to the net charge of an atom or ion. The charge numbers for ions (and also subatomic particles ) are written in superscript, e.g., Na + is a sodium ion with charge number positive one (an electric charge of one elementary ...
The charge of the resulting ions is a major factor in the strength of ionic bonding, e.g. a salt C + A − is held together by electrostatic forces roughly four times weaker than C 2+ A 2− according to Coulomb's law, where C and A represent a generic cation and anion respectively. The sizes of the ions and the particular packing of the ...
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z + is the charge number of the cation; z − is the charge number of the anion; e is the elementary charge, equal to 1.6022 × 10 −19 C; ε 0 is the permittivity of free space, equal to 8.854 × 10 −12 C 2 J −1 m −1; r 0 is the nearest-neighbor distance between ions; and