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Polysaccharides, meanwhile, have a general formula of C x (H 2 O) y where x and y are usually large numbers between 200 and 2500. When the repeating units in the polymer backbone are six-carbon monosaccharides , as is often the case, the general formula simplifies to (C 6 H 10 O 5 ) n , where typically 40 ≤ n ≤ 3000 .
Conversion between the furanose, acyclic, and pyranose forms of D-glucose Pyranose forms of some pentose sugars Pyranose forms of some hexose sugars. For many monosaccharides (including glucose), the cyclic forms predominate, in the solid state and in solutions, and therefore the same name commonly is used for the open- and closed-chain isomers.
Reducing form of glucose (the aldehyde group is on the far right). A reducing sugar is any sugar that is capable of acting as a reducing agent. [1] In an alkaline solution, a reducing sugar forms some aldehyde or ketone, which allows it to act as a reducing agent, for example in Benedict's reagent.
Polysaccharides are considered to be polymers of monosaccharides containing ten or more monosaccharide residues. [2] Polysaccharides have been given trivial names that reflect their origin. [2] Two common examples are cellulose, a main component of the cell wall in plants, and starch, a name derived from the Anglo-Saxon stercan, meaning to ...
The chair conformation of six-membered rings have a dihedral angle of 60° between adjacent substituents thus usually making it the most stable conformer. Since there are two possible chair conformation steric and stereoelectronic effects such as the anomeric effect, 1,3-diaxial interactions, dipoles and intramolecular hydrogen bonding must be taken into consideration when looking at relative ...
Polysaccharides (sugar polymers) can be linear or branched and are typically joined with glycosidic bonds. The exact placement of the linkage can vary, and the orientation of the linking functional groups is also important, resulting in α- and β-glycosidic bonds with numbering definitive of the linking carbons' location in the ring.
In an immune response, endothelial cells can express certain selectins transiently in response to damage or injury to the cells. In response, a reciprocal selectin–oligosaccharide interaction will occur between the two molecules which allows the white blood cell to help eliminate the infection or damage.
The glycosidic bond can be formed between any hydroxy group on the component monosaccharide. So, even if both component sugars are the same (e.g., glucose), different bond combinations (regiochemistry) and stereochemistry (alpha-or beta-) result in disaccharides that are diastereoisomers with different chemical and physical properties ...