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The absorption that occurs due to a transition between two states is referred to as an absorption line and a spectrum is typically composed of many lines. The frequencies at which absorption lines occur, as well as their relative intensities, primarily depend on the electronic and molecular structure of the sample.
A spectral line may be observed either as an emission line or an absorption line. Which type of line is observed depends on the type of material and its temperature relative to another emission source. An absorption line is produced when photons from a hot, broad spectrum source pass through a cooler material.
The Fraunhofer lines are a set of spectral absorption lines. They are dark absorption lines, seen in the optical spectrum of the Sun, and are formed when atoms in the solar atmosphere absorb light being emitted by the solar photosphere. The lines are named after German physicist Joseph von Fraunhofer, who observed them in 1814.
Absorption spectrum of an aqueous solution of potassium permanganate.The spectrum consists of a series of overlapping lines belonging to a vibronic progression. Spectral line shape or spectral line profile describes the form of an electromagnetic spectrum in the vicinity of a spectral line – a region of stronger or weaker intensity in the spectrum.
In spectroscopy, an absorption band is a range of wavelengths, frequencies or energies in the electromagnetic spectrum that are characteristic of a particular transition from initial to final state in a substance. According to quantum mechanics, atoms and molecules can only hold certain defined quantities of energy, or exist in specific states. [1]
The Lyman-alpha forest was first discovered in 1970 by astronomer Roger Lynds in an observation of the quasar 4C 05.34. [1] Quasar 4C 05.34 was the farthest object observed to that date, and Lynds noted an unusually large number of absorption lines in its spectrum and suggested that most of the absorption lines were all due to the same Lyman-alpha transition. [2]
A spectrum of many such photons will show an emission spike at the wavelength associated with these photons. An absorption line is formed when an atom or molecule makes a transition from a lower, E 1, to a higher discrete energy state, E 2, with a photon being absorbed in the process. These absorbed photons generally come from background ...
Atomic absorption lines are observed in the solar spectrum and referred to as Fraunhofer lines after their discoverer. A comprehensive explanation of the hydrogen spectrum was an early success of quantum mechanics and explained the Lamb shift observed in the hydrogen spectrum, which further led to the development of quantum electrodynamics .