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Hydrogenation is a chemical reaction between molecular hydrogen (H 2) and another compound or element, usually in the presence of a catalyst such as nickel, palladium or platinum. The process is commonly employed to reduce or saturate organic compounds. Hydrogenation typically constitutes the addition of pairs of hydrogen atoms to a molecule ...
The determination of the degree of hydrogenation is a critical aspect in the analysis of unsaturated compounds, particularly in polymer chemistry. The 1 H NMR technique is a primary method used to confirm hydrogenation processes and to quantify the degree of hydrogenation over varying reaction times.
Hydrogen auto-transfer, also known as borrowing hydrogen, is the activation of a chemical reaction by temporary transfer of two hydrogen atoms from the reactant to a catalyst and return of those hydrogen atoms back to a reaction intermediate to form the final product.
Hydrogen is a chemical element; it has symbol H and atomic number 1. It is the lightest element and, at standard conditions, is a gas of diatomic molecules with the formula H 2, sometimes called dihydrogen, [11] hydrogen gas, molecular hydrogen, or simply hydrogen. It is colorless, odorless, [12] non-toxic, and highly combustible.
Asymmetric hydrogenation is a chemical reaction that adds two atoms of hydrogen to a target (substrate) molecule with three-dimensional spatial selectivity.Critically, this selectivity does not come from the target molecule itself, but from other reagents or catalysts present in the reaction.
Chemistry is the scientific study of the properties and behavior of matter. [1] It is a physical science within the natural sciences that studies the chemical elements that make up matter and compounds made of atoms, molecules and ions: their composition, structure, properties, behavior and the changes they undergo during reactions with other substances.
Wilkinson's catalyst is best known for catalyzing the hydrogenation of olefins with molecular hydrogen. [ 11 ] [ 12 ] The mechanism of this reaction involves the initial dissociation of one or two triphenylphosphine ligands to give 14- or 12-electron complexes, respectively, followed by oxidative addition of H 2 to the metal.
The hydrogenation of a methenyl-H4MPT+ occurs instead of H 2 oxidation/production, which is the case for the other two types of hydrogenases. While the exact mechanism of the catalysis is still under study, recent finding suggests that molecular hydrogen is first heterolytically cleaved by Fe(II), followed by transfer of hydride to the ...
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