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In chemistry, the decay technique is a method to generate chemical species such as radicals, carbocations, and other potentially unstable covalent structures by radioactive decay of other compounds. For example, decay of a tritium -labeled molecule yields an ionized helium atom, which might then break off to leave a cationic molecular fragment.
The decay scheme of a radioactive substance is a graphical presentation of all the transitions occurring in a decay, and of their relationships. Examples are shown below. It is useful to think of the decay scheme as placed in a coordinate system, where the vertical axis is energy, increasing from bottom to top, and the horizontal axis is the proton number, increasing from left to right.
The decay energy is initially released as the energy of emitted photons plus the kinetic energy of massive emitted particles (that is, particles that have rest mass). If these particles come to thermal equilibrium with their surroundings and photons are absorbed, then the decay energy is transformed to thermal energy, which retains its mass.
Owing to these early developments, the typical example of entropy change ΔS is that associated with phase change. In solids, for example, which are typically ordered on the molecular scale, usually have smaller entropy than liquids, and liquids have smaller entropy than gases and colder gases have smaller entropy than hotter gases.
The decay energy is the mass difference Δm between the parent and the daughter atom and particles. It is equal to the energy of radiation E . If A is the radioactive activity , i.e. the number of transforming atoms per time, M the molar mass, then the radiation power P is:
There is a half-life describing any exponential-decay process. For example: As noted above, in radioactive decay the half-life is the length of time after which there is a 50% chance that an atom will have undergone nuclear decay. It varies depending on the atom type and isotope, and is usually determined experimentally. See List of nuclides.
The two types of beta decay are known as beta minus and beta plus.In beta minus (β −) decay, a neutron is converted to a proton, and the process creates an electron and an electron antineutrino; while in beta plus (β +) decay, a proton is converted to a neutron and the process creates a positron and an electron neutrino. β + decay is also known as positron emission.
The minimization of the Gibbs free energy is a form of the principle of minimum energy (minimum 'free' energy or exergy), which follows from the entropy maximization principle for closed systems. Moreover, the Gibbs free energy equation, in modified form, can be used for open systems , including situations where chemical potential terms are ...