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First-order phase transitions exhibit a discontinuity in the first derivative of the free energy with respect to some thermodynamic variable. [6] The various solid/liquid/gas transitions are classified as first-order transitions because they involve a discontinuous change in density, which is the (inverse of the) first derivative of the free ...
Ehrenfest equations (named after Paul Ehrenfest) are equations which describe changes in specific heat capacity and derivatives of specific volume in second-order phase transitions. The Clausius–Clapeyron relation does not make sense for second-order phase transitions, [ 1 ] as both specific entropy and specific volume do not change in second ...
Landau theory (also known as Ginzburg–Landau theory, despite the confusing name [1]) in physics is a theory that Lev Landau introduced in an attempt to formulate a general theory of continuous (i.e., second-order) phase transitions. [2]
Ordinal numbers may be written in English with numerals and letter suffixes: 1st, 2nd or 2d, 3rd or 3d, 4th, 11th, 21st, 101st, 477th, etc., with the suffix acting as an ordinal indicator. Written dates often omit the suffix, although it is nevertheless pronounced. For example: 5 November 1605 (pronounced "the fifth of November ...
This conclusion assumes the simplest scenario at the time of the transition, and first- or second-order transitions are possible in the presence of a quark, baryon or neutrino chemical potential, or strong magnetic fields. [12] [13] [14] The different possible phase transition types are summarised by the strong force phase diagram.
The first established thermodynamic principle, which eventually became the second law of thermodynamics, was formulated by Sadi Carnot in 1824 in his book Reflections on the Motive Power of Fire. By 1860, as formalized in the works of scientists such as Rudolf Clausius and William Thomson , what are now known as the first and second laws were ...
There are two competing arguments for second-order sea-level changes. The first states the sea level can be affected by the number of and the volume of the magma being produced at mid-ocean ridges. [6] During times of increased sea floor spreading, more magma is being produced and the volume of the ocean basins are displaced by this. This would ...
A (existential second-order) formula is one additionally having some existential quantifiers over second order variables, i.e. …, where is a first-order formula. The fragment of second-order logic consisting only of existential second-order formulas is called existential second-order logic and abbreviated as ESO, as , or even as ∃SO.