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A polyphosphate is a salt or ester of polymeric oxyanions formed from tetrahedral PO 4 structural units linked together by sharing oxygen atoms. Polyphosphates can adopt linear or a cyclic (also called, ring) structures.
Branched polyphosphoric acids give similarly branched polyphosphate anions. The simplest example of this is triphosphono phosphate [OP(OPO 3) 3] 9− and its partially dissociated versions. The general formula for such (non-cyclic) polyphosphate anions, linear or branched, is [H n+2−k P n O 3n+1] k−, where the charge k may vary from 1 to n + 2.
The specific polyphosphate generated depends on the details of the heating and annealing. One derivative is the glassy (i.e., amorphous) Graham's salt (sodium hexametaphosphate). It is a cyclic polyphosphate with the formula Na 6 [(PO 3) 6]. Crystalline high molecular weight polyphosphates include Kurrol's salt and Maddrell's salt (CAS#10361
Ammonium polyphosphate is an inorganic salt of polyphosphoric acid and ammonia containing both chains and possibly branching. Its chemical formula is H(NH 4 PO 3) n OH showing that each monomer consists of an orthophosphate radical of a phosphorus atom with three oxygens and one negative charge neutralized by an ammonium cation leaving two bonds free to polymerize.
Sodium triphosphate (STP), also sodium tripolyphosphate (STPP), or tripolyphosphate (TPP), [1]) is an inorganic compound with formula Na 5 P 3 O 10.It is the sodium salt of the polyphosphate penta-anion, which is the conjugate base of triphosphoric acid.
In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid.It most commonly means orthophosphate, a derivative of orthophosphoric acid, a.k.a. phosphoric acid H 3 PO 4.
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Polyphosphates are utilized by exopolyphosphatase enzymes, which cleave portions of the chain of phosphates. These proteins play an essential role in the metabolism and maintenance of polyphosphates. [11] Polyphosphate is located throughout the cytosol of each cell and is also present in the cell's organelles. There are many classes of ...