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To convert densities to moles per liter, multiply by 22.678 cm 3 mol/(L·g). Data obtained from CRC Handbook of Chemistry and Physics , 44th ed. pages 2560–2561, except for critical temperature line (31.1 °C) and temperatures −30 °C and below, which are taken from Lange's Handbook of Chemistry , 10th ed. page 1463.
Change in volume with increasing ethanol fraction. The molar volume of a substance i is defined as its molar mass divided by its density ρ i 0: , = For an ideal mixture containing N components, the molar volume of the mixture is the weighted sum of the molar volumes of its individual components.
The following table lists the Van der Waals constants (from the Van der Waals equation) for a number of common gases and volatile liquids. [ 1 ] To convert from L 2 b a r / m o l 2 {\displaystyle \mathrm {L^{2}bar/mol^{2}} } to L 2 k P a / m o l 2 {\displaystyle \mathrm {L^{2}kPa/mol^{2}} } , multiply by 100.
As an example, given a concentration of 260 mg/m 3 at sea level, calculate the equivalent concentration at an altitude of 1,800 meters: C a = 260 × 0.9877 18 = 208 mg/m 3 at 1,800 meters altitude Standard conditions for gas volumes
Molecular weight (M.W.) (for molecular compounds) and formula weight (F.W.) (for non-molecular compounds), are older terms for what is now more correctly called the relative molar mass (M r). [8] This is a dimensionless quantity (i.e., a pure number, without units) equal to the molar mass divided by the molar mass constant .
Some express the concentrations as ppmv (parts per million by volume) and some express the concentrations as mg/m 3 (milligrams per cubic meter), while others require adjusting or correcting the concentrations to reference conditions of moisture content, oxygen content or carbon dioxide content.
The following is a table of some constant-pressure molar heat capacities c P,m of various diatomic gases at standard temperature (25 °C = 298 K), at 500 °C, and at 5000 °C, and the apparent number of degrees of freedom f * estimated by the formula f * = 2c P,m /R − 2:
Note that the especially high molar values, as for paraffin, gasoline, water and ammonia, result from calculating specific heats in terms of moles of molecules. If specific heat is expressed per mole of atoms for these substances, none of the constant-volume values exceed, to any large extent, the theoretical Dulong–Petit limit of 25 J⋅mol ...