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Tin medal affected by tin pest. Tin pest is an autocatalytic, allotropic transformation of the element tin, which causes deterioration of tin objects at low temperatures. Tin pest has also been called tin disease, [1] tin blight, tin plague, [2] or tin leprosy. [3] It is an autocatalytic process, accelerating once it begins.
White tin may also refer specifically to β-tin, the metallic allotrope of the pure element, as opposed to the nonmetallic allotrope α-tin (also known as gray tin), which occurs at temperatures below 13.2 °C (55.8 °F), a transformation known as tin pest). White tin has tetragonal unit cell.
Metallic tin does not easily oxidize in air and water. The first tin alloy used on a large scale was bronze, made of 1 ⁄ 8 tin and 7 ⁄ 8 copper (12.5% and 87.5% respectively), from as early as 3000 BC. After 600 BC, pure metallic tin was produced.
These allotropes are known as the amorphous and the crystalline allotropes. The amorphous allotrope is a brown powder. The crystalline allotrope is gray and has a metallic luster. [16] Tin has two allotropes: α-tin, also known as gray tin, and β-tin. Tin is typically found in the β-tin form, a silvery metal.
Diamond and graphite are two allotropes of carbon: pure forms of the same element that differ in crystalline structure.. Allotropy or allotropism (from Ancient Greek ἄλλος (allos) 'other' and τρόπος (tropos) 'manner, form') is the property of some chemical elements to exist in two or more different forms, in the same physical state, known as allotropes of the elements.
This soft, brittle allotrope of arsenic has a steel gray, metallic color, and is a good conductor. [2] The rhombohedral form of this allotrope is analogous to the phosphorus allotrope black phosphorus. In its α-form, As 6 rings in chair confirmations are condensed into packed layers lying perpendicular to the crystallographic c axis. Within ...
A typical European casting alloy contains 94% tin, 1% copper and 5% antimony. A European pewter sheet would contain 92% tin, 2% copper, and 6% antimony. Asian pewter, produced mostly in Malaysia, Singapore, and Thailand, contains a higher percentage of tin, usually 97.5% tin, 1% copper, and 1.5% antimony. This makes the alloy slightly softer.
A study showed that 99.5% of the controlled food cans contain tin in an amount below that level. [4] However, un-lacquered tin cans with food of a low pH, such as fruits and pickled vegetables, can contain elevated concentrations of tin. [2] The toxic effects of tin compounds are based on its interference with iron and copper metabolism.
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