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The above value of 1.4 is highly consistent with the measured adiabatic indices for dry air within a temperature range of 0–200 °C, exhibiting a deviation of only 0.2% (see tabulation above). For a linear triatomic molecule such as CO 2 , there are only 5 degrees of freedom (3 translations and 2 rotations), assuming vibrational modes are not ...
Since the heat of combustion of these elements is known, the heating value can be calculated using Dulong's Formula: HHV [kJ/g]= 33.87m C + 122.3(m H - m O ÷ 8) + 9.4m S where m C , m H , m O , m N , and m S are the contents of carbon, hydrogen, oxygen, nitrogen, and sulfur on any (wet, dry or ash free) basis, respectively.
Note that for different gasses, the value of H n differs, according to the molar mass M: It is 10.9 for nitrogen, 9.2 for oxygen and 6.3 for carbon dioxide. The theoretical value for water vapor is 19.6, but due to vapor condensation the water vapor density dependence is highly variable and is not well approximated by this formula.
Correcting to a reference carbon dioxide content [ edit ] The following equation can be used to correct a measured pollutant concentration in an emitted gas (containing a measured CO 2 content) to an equivalent pollutant concentration in an emitted gas containing a specified reference amount of CO 2 : [ 5 ]
Data obtained from CRC Handbook of Chemistry and Physics, 44th ed. pages 2560–2561, except for critical temperature line (31.1 °C) and temperatures −30 °C and below, which are taken from Lange's Handbook of Chemistry, 10th ed. page 1463.
So for temperatures above the critical temperature (126.2 K), there is no phase transition; as pressure increases the gas gradually transforms into something more like a liquid. Just above the critical point there is a range of pressure for which Z drops quite rapidly (see the 130 K curve), but at higher temperatures the process is entirely ...
For typical applications in nuclear physics, where one particle's mass is much larger than the other the reduced mass can be approximated as the smaller mass of the system. The limit of the reduced mass formula as one mass goes to infinity is the smaller mass, thus this approximation is used to ease calculations, especially when the larger ...
Schwarzschild's equation is the formula by which you may calculate the intensity of any flux of electromagnetic energy after passage through a non-scattering medium when all variables are fixed, provided we know the temperature, pressure, and composition of the medium.