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Crystal structure of bastnäsite-(Ce). Color code: carbon, C, blue-gray; fluorine, F, green; cerium, Ce, white; oxygen, O, red. Bastnäsite, Ln III CO 3 F, is usually lacking in thorium and the heavy lanthanides beyond samarium and europium, and hence the extraction of cerium from it is quite direct.
Several of the CPK colors refer mnemonically to colors of the pure elements or notable compound. For example, hydrogen is a colorless gas, carbon as charcoal, graphite or coke is black, sulfur powder is yellow, chlorine is a greenish gas, bromine is a dark red liquid, iodine in ether is violet, amorphous phosphorus is red, rust is dark orange-red, etc.
Color code: green = Ce, gray = C, white = H. Organocerium chemistry is the science of organometallic compounds that contain one or more chemical bond between carbon and cerium. These compounds comprise a subset of the organolanthanides. Most organocerium compounds feature Ce(III) but some Ce(IV) derivatives are known.
Cerium(III) oxide, also known as cerium oxide, cerium trioxide, cerium sesquioxide, cerous oxide or dicerium trioxide, is an oxide of the rare-earth metal cerium. It has chemical formula Ce 2 O 3 and is gold-yellow in color.
Cerium(IV) oxide, also known as ceric oxide, ceric dioxide, ceria, cerium oxide or cerium dioxide, is an oxide of the rare-earth metal cerium. It is a pale yellow-white powder with the chemical formula CeO 2. It is an important commercial product and an intermediate in the purification of the element from the ores.
Cerium nitrates also form 4:3 and 1:1 complexes with 18-crown-6 (the ratio referring to that between cerium and the crown ether). Classically CAN is a primary standard for quantitative analysis. [6] [7] Cerium(IV) salts, especially cerium(IV) sulfate, are often used as standard reagents for volumetric analysis in cerimetric titrations. [8]
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