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Electron affinity can be defined in two equivalent ways. First, as the energy that is released by adding an electron to an isolated gaseous atom. The second (reverse) definition is that electron affinity is the energy required to remove an electron from a singly charged gaseous negative ion.
The electron affinity of molecules is a complicated function of their electronic structure. For instance the electron affinity for benzene is negative, as is that of naphthalene, while those of anthracene, phenanthrene and pyrene are positive. In silico experiments show that the electron affinity of hexacyanobenzene surpasses that of fullerene. [5]
The energy released when an electron is added to a neutral gaseous atom to form an anion is known as electron affinity. [15] Trend-wise, as one progresses from left to right across a period , the electron affinity will increase as the nuclear charge increases and the atomic size decreases resulting in a more potent force of attraction of the ...
the pre-exponential factor [10] in the Arrhenius Equation [11] electron affinity [10] represents the algebraic numbers [12] or affine space in algebraic geometry. A blood type; A spectral type; a represents: the first side of a triangle (opposite point A) [1] the scale factor of the expanding universe in cosmology [13]
The electron affinity (usually given by the symbol in solid state physics) gives the energy difference between the lower edge of the conduction band and the vacuum level of the semiconductor. The band gap (usually given the symbol E g {\displaystyle E_{\rm {g}}} ) gives the energy difference between the lower edge of the conduction band and the ...
where I is the ionization potential and A the electron affinity. This expression implies that the chemical hardness is proportional to the band gap of a chemical system, when a gap exists. The first derivative of the energy with respect to the number of electrons is equal to the chemical potential , μ , of the system,
The binding energy of H − equals the binding energy of an extra electron to a hydrogen atom, called electron affinity of hydrogen. It is measured to be 0.754 195 (19) eV or 0.027 7161 (62) hartree (see Electron affinity (data page)). The total ground state energy thus becomes −14.359 888 eV.
Ionization energies calculated from DFT orbital energies are usually poorer than those of Koopmans' theorem, with errors much larger than two electron volts possible depending on the exchange-correlation approximation employed. [3] [4] The LUMO energy shows little correlation with the electron affinity with typical approximations. [9]