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Worldwide production of R-22 in 2008 was about 800 Gg per year, up from about 450 Gg per year in 1998, with most production in developing countries. [2] R-22 use is being phased out in developing countries, where it is largely used for air conditioning applications. R-22 is prepared from chloroform: HCCl 3 + 2 HF → HCF 2 Cl + 2 HCl
According to ASHRAE standard 34, the R-number of a chemical refrigerant is assigned systematically according to its molecular structure and has between two and four digits. If there are carbon -carbon multiple bonds , there are four digits in all: the number of these bonds is the first digit and the number of carbon atoms minus one (C-1) is next.
Chlorodifluoromethane (R-22 or HCFC-22), a type of Freon. [9] [10] Dichlorodifluoromethane (R-12 or CFC-12), the most commonly used Freon brand refrigerant prior to its ban in many countries in 1996 and total ban in 2010. 1,1,1,2-Tetrafluoroethane (R-134a or HFC-134a), one of the main replacements for the formerly widespread R-12.
HFO-1234yf was developed by a team at DuPont, led by Barbara Haviland Minor, jointly with researchers at Honeywell. [8] [9] Their goal was to meet European directive 2006/40/EC, which went into effect in 2011 and required that all new car platforms for sale in Europe use a refrigerant in its AC system with a global warming potential (GWP) less than 150 times more potent than carbon dioxide.
R-22 HCFC-22: CHClF 2: Chlorodifluoromethane: 5280: 1760: Being phased out: A widely used hydrochlorofluorocarbon (HCFC) and powerful greenhouse gas with a GWP equal to 1810. Worldwide production of R-22 in 2008 was about 800 Gg per year, up from about 450 Gg per year in 1998. R-438A (MO-99) is a R-22 replacement. [71] R-123 HCFC-123 CHCl 2 CF 3
HCFC-123 is used in large tonnage centrifugal chiller applications, and is the most efficient refrigerant currently in use in the marketplace for HVAC applications. HCFC-123 is also used as a testing agent for bypass leakage of carbon adsorbers in gas filtration systems, and as the primary chemical in Halotron I fire-extinguishing agent. [2]
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