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Kinetic theory of gases. The temperature of the ideal gas is proportional to the average kinetic energy of its particles. The size of helium atoms relative to their spacing is shown to scale under 1,950 atmospheres of pressure. The atoms have an average speed relative to their size slowed down here two trillion fold from that at room temperature.
Maxwell–Boltzmann. In physics (in particular in statistical mechanics), the Maxwell–Boltzmann distribution, or Maxwell (ian) distribution, is a particular probability distribution named after James Clerk Maxwell and Ludwig Boltzmann. It was first defined and used for describing particle speeds in idealized gases, where the particles move ...
Thermodynamic reaction control or kinetic reaction control in a chemical reaction can decide the composition in a reaction product mixture when competing pathways lead to different products and the reaction conditions influence the selectivity or stereoselectivity. The distinction is relevant when product A forms faster than product B because ...
Continuum mechanics. Charles's law (also known as the law of volumes) is an experimental gas law that describes how gases tend to expand when heated. A modern statement of Charles's law is: When the pressure on a sample of a dry gas is held constant, the Kelvin temperature and the volume will be in direct proportion.
Thermodynamic temperature is a quantity defined in thermodynamics as distinct from kinetic theory or statistical mechanics.. Historically, thermodynamic temperature was defined by Lord Kelvin in terms of a macroscopic relation between thermodynamic work and heat transfer as defined in thermodynamics, but the kelvin was redefined by international agreement in 2019 in terms of phenomena that are ...
The internal energy is the sum of thermal kinetic energy and thermal potential energy. [12] Thus, even if the internal energy does not change, the temperature can change due to conversion between kinetic and potential energy; this is what happens in a free expansion and typically produces a decrease in temperature as the fluid expands.
The kinetic energy is equal to 1/2 the product of the mass and the square of the speed. In formula form: where is the mass and is the speed (magnitude of the velocity) of the body. In SI units, mass is measured in kilograms, speed in metres per second, and the resulting kinetic energy is in joules.
The van der Waals equation, named for its originator, the Dutch physicist Johannes Diderik van der Waals, is an equation of state that extends the ideal gas law to include the non-zero size of gas molecules and the interactions between them (both of which depend on the specific substance). As a result the equation is able to model the phase ...